Were Humans on Pangaea?

No, no species that can be related to Humans existed during the Pangea period.

What life existed on Pangea?

Life on dry land included bacteria, fungi, plants, insects, amphibians, reptiles, saurians, the early mammals, and the first birds. All of this variety evolved over hundreds of millions of years (technically billions if you count the earliest life forms).

Was there life on Earth during Pangea?

More than 200 million years ago, mammals and reptiles lived in their own separate worlds on the supercontinent Pangaea, despite little geographical incentive to do so. Mammals lived in areas of twice-yearly seasonal rainfall; reptiles stayed in areas where rains came just once a year.